Answer to Question #195814 in Molecular Physics | Thermodynamics for Muzk

Question #195814

Heliox, a breathing gas composed of a mixture of helium (He) and oxygen (O₂), is used medically for treatment in acute asthma. In medicine heliox may refer to a mixture of 21% O2 (the same as air) and 79% He. Calculate the average molar mass and density of heliox at pressure Patm = 100 kPa and room temperature t = 22°C. The molar mass of oxygen is po 16 and helium He = 4 g/mole.


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Expert's answer
2021-05-20T10:11:59-0400

Solution.

m(O2)=0.21m;m(O_2)=0.21m;

m(He)=0.79m;m(He)=0.79m;

Patm=100103Pa;P_{atm}=100\sdot10^3Pa;

T=295K;T=295K;

M(O2)=32103kg/mol;M(O_2)=32\sdot10^{-3}kg/mol;

M(He)=4103kg/mol;M(He)=4\sdot10^{-3}kg/mol;

ν=ν(O2)+ν(He);\nu=\nu(O_2)+\nu(He);

ν=0.21m32103+0.79m4103=6,53m32103=2.04102(mol);\nu=\dfrac{0.21m}{32\sdot10^{-3}}+\dfrac{0.79m}{4\sdot10^{-3}}=\dfrac{6,53m}{32\sdot10^{-3}}=2.04\sdot10^2(mol);


ν=mM    M=mν;\nu=\dfrac{m}{M}\implies M=\dfrac{m}{\nu};

M=m2.04102=5103(kg/mol);M=\dfrac{m}{2.04\sdot10^2}=5\sdot10^{-3}(kg/mol);

PV=mMRT;P=ρMRT    ρ=PMRT;PV=\dfrac{m}{M}RT; P=\dfrac{\rho}{M}RT\implies \rho=\dfrac{PM}{RT};


ρ=10010351038.31295=2.04(kg/m3);\rho=\dfrac{100\sdot10^3\sdot5\sdot10^{-3}}{8.31\sdot295}=2.04(kg/m^3);

Answer:M=5103(kg/mol);M ​ =5⋅10^ {−3} (kg/mol);

ρ=2.04(kg/m3).\rho=2.04(kg/m^3).


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