Note: Draw the P-V, T-S diagrams for all problems
13. The work required to compress a gas reversibly according to PV 1.3 =C is 68KJ. if there is no flow
determine the change in internal energy, enthalpy and heat if the gas is CO 2 .
14. Air is compressed polytropically so that the quantity PV 1.4 is constant. If 0.02 m 3 of air at atmospheric pressure of 101.3 KPA and 4C are compressed to a gage pressure of 405KPAg, determine the final temperature of air in C.
13. pV1.3 = C
Q = 0
∆U = Q - W = -W
∆H = ∆U = -68 000 J
14. pV1.4 = const
V1 = 0.02 m3; p1 = 101.3 kPa; T1 = 4°C = 4 + 273 = 277 K;
p2 = 101.3 + 405 = 506.3 kPa
p1V1n = p2V2n
p1/p2 = (V2/V1)n
101.3/506.3 = (V2/0.02)1.4
V2 = 0.006 m3
Substance is ideal gas pV = RT
T = pV/R = 506.3 x 103 Pa x 0.006 m3 / 8.31 m3 Pa K-1 = 365 K
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