The mean free path of the molecules of
a gas at 27°C is 6.0 x 10-8 m. Calculate
the pressure exerted by the gas.
The radius of the molecule is 1.8 A.
Take kB= 1.38x 10-23J K -1.
Mean free path equation λ=kT2πPdi2\lambda=\frac{kT}{\sqrt 2 \pi Pd^2_i}λ=2πPdi2kT
Where λ\lambdaλ = Mean free path of gas species
KB=Boltzmann constant
P= pressure
d= gas species diameter
T= temperature
substituting the values in the equation,
diameter of gas species=1.8×2=3.6A=3.6×10−101.8\times2=3.6A=3.6\times10^{-10}1.8×2=3.6A=3.6×10−10
6.0×10−8=1.38×10−23×3002πP×3.6×10−106.0\times10^{-8}=\frac{1.38\times10^{-23}\times300}{\sqrt2 \pi P \times 3.6\times10^{-10}}6.0×10−8=2πP×3.6×10−101.38×10−23×300
making P subject of the formula,
P=1.38×10−23×3003.6×10−10×π×2×6.0×10−8P=\frac{1.38\times10^{-23}\times300}{3.6\times10^{-10}\times\pi\times\sqrt2\times6.0\times10^{-8}}P=3.6×10−10×π×2×6.0×10−81.38×10−23×300
P=4.14×10−219.5966×10−17P=\frac{4.14\times10^{-21}}{9.5966\times10^{-17}}P=9.5966×10−174.14×10−21
P=4.314×10−5PaP=4.314\times10^{-5}PaP=4.314×10−5Pa
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