Lapse rate shows how much changes the temperature with height
Γ=−dzdT
Even in condition of thermal equilibrium, there won't be equal temperature in different layer of gas due to Boltzmann distribution. If the the gas (e.g. in atmosphere) moves in a way that PVγ= const, this processes is called adiabatic. In adiabatic atmosphere adiabatic lapse rate can be obtained.
From the first law of thermodynamics: dU=δQ−PdV
Since the processes are adiabatic, δQ=0. Also, dU=mcVdT .
From the equation of adiabatic process taking the differential: VγdP+PγVγ−1dV=0=>PdV=−γVγ−1VγdP
pdV=−γVdP
Putting all result into the first law of thermodynamics, we get
mcVdT=γVdP
Assuming an atmosphere in hydrostatic equilibrium dP=−ρgdz=−Vmgdz and taking into account γ=cp/cV we have
dT=−γcVV/m∗ρgdz=−cPgdz
Γ=−dzdT=cPg
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