A quantity of gas occupies a volume of 0.4M² a pressure of 100KN/M³ and a temperature of 20°C the gas is compressed isothermally to a pressure of 450KN/M² then expanded adiabatically to its intial volume for this quantity of gas determine;
1:the heat transferred during the compression
2:the change of internal energy during the expansion
3:the mass of gas.
"n=\\frac{R_1V_1}{RT_1}=\\frac{100*10^3*0.4}{8.314*293}=16.42mol"
"v_2=\\frac{nRT}{P_2}=\\frac{16.4*8.314*293}{450*10^3}=0.08878m^3"
(1) "Q_c=nRT_1\\ln(\\frac{V_2}{V_1})=16.42*8.314*293\\ln(\\frac{0.08878}{0.4})"
"=-60210.85kJ"
(2)"\\triangle u=\\frac{nR(T_3-T_2)}{y-1}"
But "V_3=V_1=0.4"
"P_3=P_2(\\frac{V_2}{V_3})^y=450*10^3(\\frac{0.8878}{0.4})^{1.4}"
"=54697.78"
"T_3=9.293(\\frac{54697*78}{450*10^3})^{\\frac{0.4}{1.4}}=160.46"
"\\triangle u=\\frac{16.42*8.314(160-293)}{1.4-1}=-45391.53kJ"
(3) "PV=mRT=m=\\frac{100*0.4}{8.314*293}=0.0164kg"
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