n=RT1R1V1=8.314∗293100∗103∗0.4=16.42mol
v2=P2nRT=450∗10316.4∗8.314∗293=0.08878m3
(1) Qc=nRT1ln(V1V2)=16.42∗8.314∗293ln(0.40.08878)
=−60210.85kJ
(2)△u=y−1nR(T3−T2)
But V3=V1=0.4
P3=P2(V3V2)y=450∗103(0.40.8878)1.4
=54697.78
T3=9.293(450∗10354697∗78)1.40.4=160.46
△u=1.4−116.42∗8.314(160−293)=−45391.53kJ
(3) PV=mRT=m=8.314∗293100∗0.4=0.0164kg
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