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The air-dried and sieved soil was placed into pots with a 25 cm diameter and a 27 cm height (8 kg per pot). Sulphur was used as the S source and the application rates were 0, 150, 300 mg kg−1 . The Se source was sodium selenite (Na2SeO3) and it was applied at 0 and 15 mg kg−1.


I will like to understand how they got the amount of selenite and sulphur added to the pot experiment?


An experimental data on the reaction of H2 and PO3-3 is given below:

Experiment No. Initial [PO3-3] Initial [H2] Initial Rate

1 0.100 0.100 1.50

2 0.200 0.100 3.00

3 0.100 0.200 6.00

a.  What is the order of reaction with respect to [PO3-3]?

b.  What is the order of reaction with respect to [H2]?

c.  What is the overall reaction?


b) Discuss the role of activating, deactivating and protecting groups briefly in organic synthesis.

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Draw the Jabslonski diagram showing excitation and deactivation routes.

With suitable examples explain [2+2] and [4+2] cycloaddition reactions.

What are the motivating factors for the Wagner-Meerwein rearrangement? Discuss its mechanism with a suitable example.

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The elimination of HCl from chlorofumaric acid is 50 times faster than from chloromalic acid. Explain.

Define the Saytzeff rule

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