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What do you understand by syn-elimination and anti-elimination. Explain with a suitable example.

ESSAY.


Water, compared to other substances, has one of the highest specific heat values. What is the advantage of this fact for the human body?



Direction: Solve the following problems. Attach your solutions.


1. Calculate the standard enthalpy change ΔH°, for the following reaction:



2CH3OH (l) + 3O2 (g) --> 2CO2 (g) + 2H2O (g)



Given: CH3OH (l) -------> ΔHf° = -238.7 kJ


CO2 (g) -------> ΔHf° = -393.5 kJ


H2O (l) -------> ΔHf° = -285.8 kJ

Aldehyde without  - hydrogen does not undergo Cannizzaro reaction. ii) For Michael addition electron withdrawing group must be present with carbon – carbon double bond.

What is meant by thermodynamic and kinetic control in chemical reactions? Explain taking an example of addition of HCl to 1, 3-butadiene.

How is the nucleophilicity different from the basicity? Explain with the help of an example.

1.Calculate the enthalpy change for the following chemical reaction:

SC2(l) + 3O@(g) --> CO2(g) + 2SO2(g)


1.C(s) + O2(g) --> CO2(g) ΔH° = - 393.5 kJ

2.S(s) + O2(g) --> SO2(g) ΔH° = - 296.8 kJ

3.C(s) + 2S(s) --> CS2(l) ΔH° = + 87.9 kJ


a pot of cold water is heated on a stove, and when the water boils, a fresh egg is placed in the water to cook. describe the events that are occuring in terms of the zeroth law of thermodynamics.

How many moles are there in 8.25 x 1026 molecules of methane, CH4?

How many moles are there in 8.25 x 1026 molecules of methane, CH4?





Calculate the heat released when 68.0 gram of steam at 1240C is converted to water

    at 450C


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