A 25.ID-mL sample containing Fe³° and Cu°° required
16.06 mL of 0.050 83 M EDTA for complete titration. A 50.IXI-mL sample of the unknown was treated
with NH F to protect the Fe°°. Then Cu²° was reduced and masked by thiourea. Addition of
25.00 mL of 0.050 83 M EDTA liberated Fe from its fluoride complex to form an EDTA complex. The
excess EDTA required
19.77 mL of 0.018 83 M Pb'+ to reach a xylenol orange end point.
Find (Cu' ) in the unknown.
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