A glass sphere is filled to full volume with a gas. The pressure of the gas inside the sphere is 30.0 atm, and the temperature is 30.0°C. The sphere is taken outside on a cold day. The temperature of the gas decreases to 10.0°C. What is the new pressure of the gas? Assume that the volume is constant.
P1 = 30.0 atm
T1 = 30.0°C + 273 = 303 K
V1 = V2 = const
P2 = unknown
T2 = 10.0°C + 273 = 283 K
Solution:
Since the volume doesn't change, Gay-Lussac's Law can be used.
Gay-Lussac's Law can be expressed as: P1/T1 = P2/T2
P1T2 = P2T1
To find the final pressure, solve the equation for P2:
P2 = P1T2/T1
P2 = (30.0 atm × 283 K) / (303 K) = 28.0198 atm = 28.0 atm
P2 = 28.0 atm
Answer: 28.0 atm is the new pressure of the gas.
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