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There are two forms of glucose, designated alpha (a) and beta (b), which are in equilibrium in aqueous solution. The equilibrium constant for the reaction is 1.5 at 30°C.


a-D-glucose(aq) <=> b-D-glucose(aq) K=1.5


(a) If you begin with a fresh 1.0 M solution of a-D-glucose in water, what will be its concentration when equilibrium is reached?


(b) Calculate the percentage of a-glucose and of b-glucose present at equilibrium in aqueous solution at 30°C.
For the reaction A + B  C, the rate constant at 215 oC is 5.0 x 10-3 and the rate constant at 452o C is 1.2 x 10-1.

3



(a) What is the activation energy in kJ/mol? (b) What is the rate constant at 100o C.
A buffered solution contains 0.25 M NH3 (Kb = 1.8 x 10-5) and 0.40 M NH4Cl. a. Calculate the pH of this solution. b. Calculate the pH of the solution that results when 0.10 mole of gaseous HCl is added to 1.0 L of the buffered solution from part a.
The autoionization of sulfuric acid can be described by the following chemical equation: H2SO4 (l) + H2SO4 (l) ⇌ H3SO4+(aq) + HSO4− (aq) At 25°C, K = 3 × 10−4. a. Write an equilibrium constant expression for K H2SO4 that is analogous to Kw.



Given that the density of H2SO4 is 1.8 g/cm3 at 25°C. b. What is the concentration of H3SO4+ ? c. What fraction of H2SO4 is ionized?
Describe the ways of classifying amino acids and give example of each class
If you used 61.5mL of 3.80 M KOH to titrate 15.0 ML of H2SO4, what was the concentration of the H2SO4?.
How many liters of ammonia gas is generated with 4.50 L of nitrogen gas and excess hydrogen gas?
What is the maximum mass of

S

8

that can be produced by combining

75.0

g

of each reactant?


8

SO

2

+

16

H

2

S



3

S

8

+

16

H

2

O
Why iis balanced chemical equation needed in solving stoichiometric calculation?
Give the statementss of Zeroth,First, second and third laws of thermodynamics and outline their significant
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