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3. Adding HCl to the above amines make them all soluble in water. Write the equations for the addition of HCl to the amines, and describe why the addition of HCl makes them all soluble in water


a. 1-butanamine


b. N-methyl-1-butanamine


c. N,N-dimethylbutanamine


d. Why do these reactions increase their solubility?



2. 1-butanamine and N-methyl-1-butanamine are soluble in water, whereas N,N-dimethylbutanamine is not soluble. Describe why the molecules have different solubilities, indicating on the structural formulas above potential site for H-bonding with water.



B. Solubility of Amines in Water and Acid


1. Draw structural formulas of the following molecules. Include the lone pair of electrons.


a. 1-butanamine


b. N-methyl-1-butanamine


c. N,N-dimethylbutanamine



A. Structure of Primary, Secondary, Tertiary amines.


  1. Use your model kit to build the following structures. Sketch the structures and indicate whether they are primary, secondary or tertiary amines.

a. Methanamine


b. N,N-dimethylmethanamine


c. N,N,N-trimethylmethanamine



0.06g of a monobasic acid having the general formula C.HCOOH was neutralised by 100cm of 0.01mol dm NaOH solution. What is the molecular formula of the acid?


Explain the main principle of enzymodiagnostics. Give the examples.
Structure of
Benzene->2,5-dibromobenzene
P-xylene->2,5-chlorophitalic acid
What is sigma and pie complex
Choose coenzymes taking part in group transfer: ascorbic acid, NADPH,
pyridoxal phosphate, tetrahydrofolic acid
Flask A contains 0.5 L of Ar gas at 1.5 bar and 0 oC, and flask B contains 300 mL of N2 gas at 700 torr and 100 oC. After the two gases are mixed together in a 0.4 L flask at 298 K, what are the partial pressures of the two gases and the total pressure of the gas inside the flask? Assume ideal gas behaviour. Show your calculations.
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