Calcium carbonate decomposes at high temperatures to form carbon dioxide and calcium oxide. What mass of CaCO3 would be needed to produce 3.45L of CO2 at 1.0 atm and 289K?
CaCO3 → CO2 + CaO
"V=3.45 \\;L \\\\\n\np= 1.0 \\;atm \\\\\n\nT = 289 \\;K"
Ideal gas law
pV =nRT
R = 0.08206 L×atm/mol×K
"n = \\frac{pV}{RT} \\\\\n\nn(CO_2) = \\frac{1.0 \\times 3.45}{0.08206 \\times 289} = 0.145 \\;mol"
According to the reaction:
n(CaCO3) =n(CO2) = 0.145 mol
MM(CaCO3) = 100.08 g/mol
m(CaCO3) "= 0.145 \\times 100.08 = 14.56 \\;g"
Answer: 14.56 g
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