The mass concentration of 50.6% means that 50.6 grams of the substance can be dissolved in 100 g of water. 100 ml of water weigh 100 g.
According to the solubility-temperature table on Wikipedia, maximum solubility of this substance in water at 100°C is 41 g per 100 ml of water. Since the temperature of solution (in liquid phase) cannot be greater than 100°C (boiling point of water), some data is incorrect.
References
https://en.wikipedia.org/wiki/Solubility_table
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