one mole of an ideal monoatomic gas is taken through the cycle shown in the figure.
the process A:B is a reversible isothermal expansion.
Given. P(A)=5atm V(A)=10litre
P(B)=1atm V(B)=50litre
P(C)=1atm V(C)=10liter
calculate the net work done by the gas
Solution.
"P_A=5atm=506625Pa;"
"V_A=10L=0.01m^3;"
"P_B=1atm=101325Pa;"
"V_B=50L=0.05m^3;"
"P_C=1 atm=101325Pa;"
"V_C=10L=0.01m^3;"
"P_AV_A=\\nu RT_A\\implies T_A=\\dfrac{P_AV_A}{\\nu R};"
"T_A=\\dfrac{506625\\sdot0.01}{1\\sdot8.31}=609.66K;"
"P_CV_C=\\nu RT_C\\implies T_C=\\dfrac{P_CV_C}{\\nu R};"
"T_C=\\dfrac{101325\\sdot0.01}{1\\sdot8.31}=121.93;"
"A=A_{AB}+A_{BC};"
"A_{AB}=\\nu RTln\\dfrac{V_2}{V_1};"
"A_{AB}=1\\sdot8.31\\sdot609.66\\sdot ln\\dfrac{0.05}{0.01}=8153.7J=8.1537kJ;"
"A_{BC}=P_B(V_C-V_B);"
"A_{BC}=101325\\sdot(0.01-0.05)=-4053J=-4.053kJ;"
"A=8.1537-4.053=4.045kJ;"
Answer: "A=4.045kJ."
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