one mole of an ideal monoatomic gas is taken through the cycle shown in the figure.
the process A:B is a reversible isothermal expansion.
Given. P(A)=5atm V(A)=10litre
P(B)=1atm V(B)=50litre
P(C)=1atm V(C)=10litre
Calculate
the energy expelled by the gas.
Solution.
"\\nu=1 mol;"
"P_A=5 atm=506625Pa;"
"V_A=10L=0.01m^3;"
"P_B=1atm=101325Pa;"
"V_B=50L=0.05m^3;"
"P_C=1 atm=101325 Pa;"
"V_C=10L=0.01m^3;"
"P_AV_A=\\nu RT_A\\implies T_A=\\dfrac{P_AV_A}{\\nu R};"
"T_A=\\dfrac{506625\\sdot0.01}{1\\sdot8.31}=609.66K;"
"P_CV_C=\\nu RT_C\\implies T_C=\\dfrac{P_CV_C}{\\nu R};"
"T_C=\\dfrac{101325\\sdot0.01}{1\\sdot8.31}=121.93K;"
"\\Delta U=\\dfrac{3}{2}\\nu R \\Delta T;"
"\\Delta U=\\dfrac{3}{2}\\sdot1\\sdot8.31\\sdot(121.93-609.66)=-6.08kJ;"
Answer: "\\Delta U=-6.08kJ."
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