Question #178359

the normalized wave function for the first excited state of particle in one dimensional box


1
Expert's answer
2021-04-08T07:35:47-0400

The wave function can be written as

Ψn(x)=Ansin(nπxL)\Psi_n(x)=A_nsin(\dfrac{n\pi x}{L})


The constant AnA_n is determined by normalization condition

Ψn2dx=An2sin2(nπxL)dx=1\int\Psi^2_n dx=\int A_n^2sin^2(\dfrac{n\pi x}{L})dx=1


The result of evaluating the integral and solving for An=2LA_n=\sqrt{\dfrac{2}{L}} is independent from n.


The normalized wave function for a particle in a box are thus

Ψn(x)=2Lsin(nπxL)\Psi_n(x)=\sqrt{\dfrac{2}{L}}sin(\dfrac{n\pi x}{L})

For first excited state n = 2

 Ψ2(x)=2Lsin(2πxL)\therefore\space \Psi_2(x)=\sqrt{\dfrac{2}{L}}sin(\dfrac{2\pi x}{L})



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