Three spin less non-interacting distinguishable particles, with respective masses 𝑚1, 𝑚2, and 𝑚3 in the ratio 𝑚1: 𝑚2: 𝑚3 = 1: 2: 3, are subject to a common infinite square well potential of width L in one spatial dimension. Determine the energies and the corresponding wave functions in the lowest two energy states of the system.
Answer
common infinite square well potential of width L in one spatial dimension
Energy is given
"E_n=\\frac{n^2\\pi^2\\hbar^2}{2mL^2}"
Wavefunction
"\\psi=\\sqrt{\\frac{2}{L}}sin(\\frac{n\\pi x}{L})"
According to given data total energy of system is given
For ground state n=1
"E_1=\\frac{n^2\\pi^2\\hbar^2}{2m_1L^2}+\\frac{n^2\\pi^2\\hbar^2}{2m_2L^2}+\\frac{n^2\\pi^2\\hbar^2}{2m_3L^2}"
"E_1=" "\\frac{7\\pi^2\\hbar^2}{8mL^2}"
First excited state n=2
"E_2=\\frac{n^2\\pi^2\\hbar^2}{2m_1L^2}+\\frac{n^2\\pi^2\\hbar^2}{2m_2L^2}+\\frac{n^2\\pi^2\\hbar^2}{2m_3L^2}"
="E_1=\\frac{7\\pi^2\\hbar^2}{2mL^2}"
Now wavefunction
"\\psi_1=\\sqrt{\\frac{2}{L}}sin(\\frac{\\pi x}{L})"
And
"\\psi_2=\\sqrt{\\frac{2}{L}}sin(\\frac{2\\pi x}{L})"
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