We know that the band bending is the difference of the work function of the p-type and n-type material. so,
qVbi=qϕp−qϕn
We know that total band bending is the intrinsic level is the build in potential,
⇒Eip−Ein=qVbi
⇒(Eip−EF)−(Ein−EF)=qVbi
In the case of equilibrium,
Eip−EF=qϕp
and EF−Ein=qϕn
Hence, we can write it as,
⇒qϕp+qϕn=qVbi
From the Fermi Dirac statistics,
pPo=nieRTEi−EF
nno=nieRTEi−EF
In the case of full ionization,
Ppo=NA and nno=ND
So, we can write,
qFp+qFn=KT[ln(niNA)+ln(niND)]
Hence, we can write,
qVbi=KTlnni2NAND
Now, calculating the depletion region width
Vbi=∫−xpxnE.dx
E=ϵqNAxp
Hence, Vbi=(2xp+xn)ϵqNAxp
But, NAxp=NDxn
Hence, qNA2ϵ=NANA+NDxp2
So, xp=q2ϵNANDNA+ND1Vbi
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