The force cannot exist itself, it is always acting on something. So let's suppose that we put some charge Q in the centre of the square and find force acting on this charge in centre.
- Let's assume that Q<0, then the picture looks like on the drawing above.Coulomb forces that acting on -Q are "F_1, F_2, F_3, F_4". Since all +q are equal, all forces "F_1, F_2, F_3, F_4" have equal modulus, but different directions. Vector sum "F_1+F_2+F_3+F_4=0" as can be seen from the drawing. However, note that +q will not be in equilibrium for any Q, because +q experience Coulomb force from interaction with other +q charges ("F_x" and "F_y" in the picture). So, all +q will be repulsing while -Q remain is centre.
- Let's assume Q>0, then forces from the picture will change their direction to opposite. But the sum "F_1+F_2+F_3+F_4" still remains zero. In this case for any value of +Q, system of +q will begin repulsing from central +Q while +Q remains at its place.
Answer: "F = \\sum F_i=0"
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