The force cannot exist itself, it is always acting on something. So let's suppose that we put some charge Q in the centre of the square and find force acting on this charge in centre.

- Let's assume that Q<0, then the picture looks like on the drawing above.Coulomb forces that acting on -Q are F1,F2,F3,F4. Since all +q are equal, all forces F1,F2,F3,F4 have equal modulus, but different directions. Vector sum F1+F2+F3+F4=0 as can be seen from the drawing. However, note that +q will not be in equilibrium for any Q, because +q experience Coulomb force from interaction with other +q charges (Fx and Fy in the picture). So, all +q will be repulsing while -Q remain is centre.
- Let's assume Q>0, then forces from the picture will change their direction to opposite. But the sum F1+F2+F3+F4 still remains zero. In this case for any value of +Q, system of +q will begin repulsing from central +Q while +Q remains at its place.
Answer: F=∑Fi=0
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