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Question #85734
The pressure P, Volume V and Temperature T of a mole of an ideal gas are related by the
equation PV = 8.31 T. Find the rate at which the pressure is changing when the
temperature is 300k and increasing at a rate of 0.1 per second and the volume is 100 L and
increasing at the rate of 0.2 per second.
Expert's answer
P=8.31 T/V; T = 300K; V = 100L = 0.1 m^3;
d
T
d
t
=
0.1
K
/
s
e
c
;
d
V
d
t
=
0.2
L
/
s
e
c
=
2
∗
1
0
−
4
m
3
/
s
e
c
\frac{d T}{d t} = 0.1 K/sec; \frac{d V}{d t} = 0.2 L/sec = 2*10^{-4} m^3/sec
d
t
d
T
=
0.1
K
/
sec
;
d
t
d
V
=
0.2
L
/
sec
=
2
∗
1
0
−
4
m
3
/
sec
d
P
d
t
=
∂
P
∂
T
d
T
d
t
+
∂
P
∂
V
d
V
d
t
=
8.31
V
d
T
d
t
−
8.31
T
V
2
d
V
d
t
\frac{d P}{d t} = \frac{\partial P}{\partial T} \frac{d T}{d t} + \frac{\partial P}{\partial V} \frac{d V}{d t} = \frac{8.31}{V}\frac{d T}{d t} -\frac{8.31T}{V^2}\frac{d V}{d t}
d
t
d
P
=
∂
T
∂
P
d
t
d
T
+
∂
V
∂
P
d
t
d
V
=
V
8.31
d
t
d
T
−
V
2
8.31
T
d
t
d
V
d
P
d
t
=
8.31
0.1
0.1
−
8.31
∗
300
0.1
∗
0.1
2
∗
1
0
−
4
=
−
41.55
P
a
/
s
e
c
\frac{d P}{d t} =\frac{8.31}{0.1} 0.1 - \frac{8.31*300}{0.1*0.1} 2*10^{-4}=-41.55 Pa/sec
d
t
d
P
=
0.1
8.31
0.1
−
0.1
∗
0.1
8.31
∗
300
2
∗
1
0
−
4
=
−
41.55
P
a
/
sec
The pressure decreases at the rate 41.55 Pa per second.
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