Question #72721

A piston cylinder contains gas initially at 3500 kPa with a volume of 0.03 cubic meter. The gas is compressed during a process where pV raise to 1.25 = C to a pressure of 8500 kPa. The heat transfer from the gas is 2.5 kJ. Determine the change in internal energy, neglecting changes in kinetic and potential energies. Graph a PV and TS Plane.

Expert's answer

Answer on Question #72721, Engineering / Mechanical Engineering

A piston cylinder contains gas initially at 3500kPa3500\,\mathrm{kPa} with a volume of 0.03 cubic meter. The gas is compressed during a process where pV raise to 1.25=C1.25 = C to a pressure of 8500kPa8500\,\mathrm{kPa}. The heat transfer from the gas is 2.5kJ2.5\,\mathrm{kJ}. Determine the change in internal energy, neglecting changes in kinetic and potential energies. Graph a PV and TS Plane.

Solution:

The polytropic process is one in which the pressure-volume relation is given as


pVn=constantp V^n = \text{constant}


In our case,


pV1.25=constantp V^{1.25} = \text{constant}p1V11.25=p2V21.25p_1 V_1^{1.25} = p_2 V_2^{1.25}


Thus,


V2=V1(p1p2)11.25=0.03(35008500)11.25=0.01475m3V_2 = V_1 \left(\frac{p_1}{p_2}\right)^{\frac{1}{1.25}} = 0.03 \left(\frac{3500}{8500}\right)^{\frac{1}{1.25}} = 0.01475\,\mathrm{m}^3


The work done during the polytropic process is found by substituting the pressure volume relation into the boundary work equation. The result is


W=12pdV=p2V2p1V11nW = \int_1^2 p\,dV = \frac{p_2 V_2 - p_1 V_1}{1 - n}


So,


W=8500×103×0.014753500×103×0.0311.25=81500JW = \frac{8500 \times 10^3 \times 0.01475 - 3500 \times 10^3 \times 0.03}{1 - 1.25} = -81500\,\mathrm{J}


Then, according to the first law of thermodynamics,


ΔU=QW\Delta U = Q - W


where ΔU\Delta U is the change in the internal energy of the system and WW is work done by the system.


ΔU=2500+81500=79000J=79kJ\Delta U = -2500 + 81500 = 79000\,\mathrm{J} = 79\,\mathrm{kJ}


Answer: ΔU=79kJ\Delta U = 79\,\mathrm{kJ}

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