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a. What are the limitations of Arrhenius definition of acids and bases?


b. What similarity does Arrhenius have with Bronsted-Lowry definition?


c. How does it improve Arrhenius’ definition? Post-viewing questions:


a. What is Bronsted and Lowry’s definition of acids and bases?


b. How does it impact chemistry?


c. Based on Bronsted’s definition, explain the relation between H+, acids and base.


Iron can be extracted from haematite, Fe2O3, using either C or CO2 as the reducing agent. The reactions are shown below.


Fe2 O3 (s) + 3 C(s) → 2 Fe(s) + 3 CO(g) ΔH = +492.7 kJ /mol Fe2 O3 (s) + 3 CO(g) → 2 Fe(s) + 3 CO2 (g) ΔH = - 24.8 kJ/mol Substance S° (J/ K·mol) Fe2 O 3 (s) 87.4 Fe (s) 27.3 C (s) 5.7 CO (g) 197.6 CO 2 (g) 213.6 Use available data given to:


1. Calculate the minimum temperature at which reduction with carbon is feasible


2. Prove by calculation that reduction with carbon monoxide is feasible at all temperatures.


4 Titration of 0.2121 g of pure Na2C2O4 required 43.31 mL of KMnO4. What is the molar concentration of the KMnO4 solution? The chemical reaction is MnO4- + C2O42- + H+ ----------> Mn2+ + CO2 + H2O (unbalanced equation) Atomic masses: Na = 23 C = 12 O = 1

1 . What is the concentration of HCl if it takes 63.0mL of 0.1 M NaOH to neutralize 140mL of the acid?


2 . If it takes 58.5mL of of 0.5 M potassium hydroxide to neutralize 135 mL of sulfuric acid, what is the concentration of the acid?


3 Describe the preparation of 2.00 L of 0.0500 M AgNO3 from the primary standard grade solid. Atomic masses: Ag = 108 N = 14 O =16



1.What is the concentration of HCl if it takes 63.0mL of 0.1 M NaOH to neutralize 140mL of the acid?


2. If it takes 58.5mL of 0.5 M potassium hydroxide to neutralize 135 mL of sulfuric acid, what is the concentration of the acid?


3. Describe the preparation of 2.00 L of 0.0500 M AgNO3 from the primary standard grade solid. Atomic masses: Ag = 108 N = 14 O =16



The molar cconcentration of a solution of ammonium molibdate in an aqueous solution which contains 48 parts per million of MoMolybdenum is?


If that a chunk of potassium weighing 7.55g is dropped into 400.0g of water at 25°C, what is the final temperature (in °C) of the water if all the heat released is used to warm the water?


if p1=4 atm and v1=3 l, what will v2 be if p2=7.3 atm?






What unit is used to describe reaction rate?



Explain in detail the Crystal Field Theory. Using


examples where applicable, how does the theory


explain the following for a transition metal complex;


1.The structure.


2.Colours behavior


3.Compound formation


4.Magnetic properties


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