Assuming that the oxygen gas is collected at P = 755 mm Hg and T = 305 K with the chemical equation 2KClO3(s) → 2KCl(s) + 3O2(g), how many liters of oxygen gas are produced when 294 g of KClO3 completely react as used in the ignition of fireworks? Solve to get the correct answer
Solution:
Calculate the moles of KClO3:
The molar mass of KClO3 is 122.55 g/mol
Hence,
(294 g KClO3) × (1 mol KClO3 / 122.55 g KClO3) = 2.399 mol KClO3 = 2.4 mol KClO3
Balanced chemical equation:
2KClO3 → 2KCl(s) + 3O2(g)
According to stoichiometry:
2 mol of KClO3 produces 3 mol of O2
Thus, 2.4 mol of KClO3 produces:
(2.4 mol KClO3) × (3 mol O2 / 2 mol KClO3) = 3.6 mol O2
The ideal gas law can be used: PV = nRT
To find the volume of O2, solve the equation for V:
V = nRT/P
V(O2) = (3.6 mol × 62.3637 L mmHg mol-1 K-1 × 305 K) / (755 mmHg) = 90.6958 L = 90.7 L
V(O2) = 90.7 L
Answer: 90.7 liters of oxygen gas are produced.
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