What is the hydronium-ion concentration of a 0.01 F solution of H2CO3 if only the primary ionization reaction is considered.
The dissociation occurs as follows:
H2CO3 + H2O = H3O+ + HCO3-
According to the expression:
Ka = [H3O+] [HCO3-] / [H2CO3]
As Ka2 = 2.5 × 10-4, the hydronium-ion concentration equals:
[H3O+] × [H2CO3] = Ka / [HCO3-] = 0.01 F × 2.5 × 10-4 = 2.5 × 10-6
[H3O+]2 = 2.5 × 10-6
[H3O+] = 0.0016 F
Answer: 0.0016 F
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