For a liquid obeying the equation ofstate Vm
= c1 + c2T+c3T2 -c4P− c5PT,findexpressionsfor each
of the following propertiesin terms ofthe c’s,CP,P, T, andV: (a)CP
-CV
;(b)(
0.2 kg of water at 59oC is added to 0.4 kg of water at 20oC in a polystyrene cup. What is
the final temperature of the mixture?
(s.h.c. of water is 4200 J/kg/oC )
An isolated system contains 900 g of ice at 0 C. A hot iron block (2.5 kg and CP = 500 Cal C-1)
at 200 C was immersed in the isolated system containing ice. A following reaction gives the
enthalpy change of 1440 Cal mol-1. [Cp,m for H2O (l) = 18.0 Cal C-1 mol-1]
H2O(s) H2O(l)
Find;
(a) Final temperature of isolated system
(b) The entropy change of iron and water
(c) Total entropy and briefly explain.
Ammonia,carbon dioxide and water react together to form ammonium carbonate.
Which statement about this reaction is correct?
A.It is a redox reaction
B.It is an acid-base reaction
Consider the carbonate ion, CO32-
i) Setup and solve the Huckel secular equations for the pi-electrons.
ii) Express the energies in terms of the Coulomb integrals]
iii) Determine the delocalization energy.