At the first let's find the molar mass of "{P_2}{O_5}" - it can be calculated as the sum of atomic weights taking into account the number of atoms of each type in the molecule
"{M_{{P_2}{O_5}}} = 2{M_P} + 5{M_O} \\approx 2 \\cdot 16[\\frac{{\\rm{g}}}{{{\\rm{mol}}}}] + 5 \\cdot 30.97[\\frac{{\\rm{g}}}{{{\\rm{mol}}}}] = 141.94[\\frac{{\\rm{g}}}{{{\\rm{mol}}}}]"(atomic weights of atoms "P" and "O" can be found in periodic table and respectively equal to "30.97[\\frac{{\\rm{g}}}{{{\\rm{mol}}}}]" and "16[\\frac{{\\rm{g}}}{{{\\rm{mol}}}}]")
The number of moles in "0.220[{\\rm{g}}]" of "{P_2}{O_5}" can be found as
Now let's use that there are "{N_A} \\approx 6.022 \\cdot {10^{23}}[\\frac{1}{{{\\rm{mol}}}}]" (particles per 1 mole). In our case it will be the number of molecules. But to find the total number of atoms we can notice that there are "7" atoms in "1" molecule of "{P_2}{O_5}" (2 atoms of "P" and 5 atoms of "O"). Thus the total number of atoms is
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