At the first let's find the molar mass of P2O5 - it can be calculated as the sum of atomic weights taking into account the number of atoms of each type in the molecule
MP2O5=2MP+5MO≈2⋅16[molg]+5⋅30.97[molg]=141.94[molg] (atomic weights of atoms P and O can be found in periodic table and respectively equal to 30.97[molg] and 16[molg])
The number of moles in 0.220[g] of P2O5 can be found as
ν=MP2O5m=141.94[molg]0.220[g]≈1.55⋅10−3[mol] Now let's use that there are NA≈6.022⋅1023[mol1] (particles per 1 mole). In our case it will be the number of molecules. But to find the total number of atoms we can notice that there are 7 atoms in 1 molecule of P2O5 (2 atoms of P and 5 atoms of O). Thus the total number of atoms is
N=7νNA=7⋅1.55⋅10−3[mol]⋅6.022⋅1023[mol1]≈6.53⋅1021
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