Fe(NO3)3 (aq) + Na3PO4 (aq) --> FePO4 + 3NaNO3 (aq) assuming a percentage yield of 90 percent, what mass of ferric nitrate must be reacted with an excess of sodium phosphate to produce 54 g of ferric phosphate? The MWs are Fe(NO3)3 = 242 g, and FePO4 is 151 g.
Solution. We find the amount of iron phosphate: n(FePO4)=M(FePO4)m(FePO4), where m(FePO4) - mass of iron phosphate, g; M(FePO4) - molar weight of iron phosphate, g/mol. Then n(FePO4)=15154=0.36 mol. By the reaction equation at 100% reaction yield n(FePO4)=n(Fe(NO3)3). In this case, we have a yield of 90%, then n(Fe(NO3)3)=0.9n(FePO4)=0.90.36=0.4 mol. The mass of iron nitrate is calculated as: m(Fe(NO3)3)=n(Fe(NO3)3)×M(Fe(NO3)3)=0.4×242=96.8 g.
Answer: 96.8 g.
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