c(CH3COOH)=35.29mL*0.205M/24.37 mL =0.30M
CH3COOH+NaOH"\\to" CH3COONa+H2O
c(CH3COONa )=0.3М
pKa(CH3COOH)=4.76
pH=7+0.5*4.76+0.5*lg(0.3)=9.12
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