5g of NaOH and NaCL ( as impurity) were dissolved in 1dm3 of water. If 25cm3 of this solution were neutralized by 21cm3 of 0.1moldm3 HCL. Calculate the mass concentration of NaOH in gdm3.
NaOH + HCl ==> NaCl + H2O
Converting volumes from cm3Â to dm3:
volume of HCl = 21.0 cm3 = 21.0 ÷ 1000 = 0.021 dm3
volume of NaOH = 25.0 cm3 = 25.0 ÷ 1000 = 0.025 dm3
Amount of HCl in mol = concentration in mol/dm3 × volume in dm3
= 0.1 mol/dm3 × 0.021 dm3
= 0.0021 mol
The equation shows that 1 mol of HCl reacts with 1 mol of NaOH. So the amount of NaOH in 25.0 cm3Â is 0.0021 mol.
[NaOH] = 0.0021 mol / 0.025 dm3 = 0.084 mol/dm3
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