The pkas of two monoprotic acods HA and HB are 5.9 and 8.1 respectively. Which of the two is the stronger acid?
pKa(HA) = 5.9; Ka(HA) = 10-5.9;
pKa(HB) = 8.1; Ka(HB) = 10-8.1;
Therefore, the higher value pKa correspond the lower value Ka and the lower value pKa correspond the higher value Ka.
Ka = [H+] * [A-] / [HA]
[H+] =Ka * [HA] / [A-]
Therefore, the higher value Ka correspond the stronger acid.
So, HA is the stronger acid with the value pKa 5.9.
Answer: HA.
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