1. An 600.0-mg sample of chromium ore was dissolved and the chromium oxidized to chromate ion. The solution was treated with 15.00 mL of 0.1750 M AgNO3. The resulting precipitate of AgCr2O4 was removed and discarded. The excess AgNO3 required 12.50 mL of 0.1240 M KSCN for titration. The pertinent ionic reactions are:
Cr2O42-+ 2Ag+→ Ag2CrO4(s)
Ag++ SCN-→ AgSCN (s)
Calculate the % Cr2O3 in the ore.
Molar Mass of ore = 159.69
600 mg = 600g
600/159.69
= 3.76M
Molar Mass of AgNO3 = 169.87
0.1750 × 169.87
= 29.73 × 12.5
= 371.591
=(371.591/600)100
= 61.93%
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