The mass of magnesium hydroxide, Mg(OH)2, in an indigestion tablet was determined as
follows:
Step 1 The tablet was crushed and dissolved in exactly 40.00 cm3
of 0.5M
Hydrochloric acid (an excess).
Mg(OH)2(s) + 2HCl(aq) ïƒ MgCl2(aq) + 2H2O(l)
Step 2 The amount of hydrochloric acid remaining was measured by titration with
0.250 mol dm–3
sodium hydroxide solution.
22.80 cm3
of this sodium hydroxide solution was required.
Calculate the mass of magnesium hydroxide in the tablet.
total mmol of HCl = 40×0.5 = 20 mmol
mmol of HCl remaining = 0.250×22.80 = 5.7
mmol
moles of HCl reacted with Mg(OH)2 =
20 - 5.7 = 14.3 mmol
mmol of Mg(OH)2 required = 14.3/2 = 7.15 mmol
mass of Mg(OH)2 = (7.15/100)×58.3 = 0.4168g
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