[By calcium sulfate I believe is meant copper sulfate?]
Cu + 2H2SO4 —> CuSO4 + SO2 + 2H2O
Mass of sulfuric acid = 40kg = 40000g
Molar mass of sulfuric acid = 196g/mol
∴ No of moles of sulfuric acid = 204mol/dm3
If 2 mole of H2SO4 reacts with 1 mole of Cu, it means 204 moles of H2SO4 will react with 102 moles of Cu.
Mass of Cu therefore required = No of moles of Cu (102) * Molar mass of Cu (63.5) = 6477g = 6.477kg
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