In order to understand how much N2 can be produce, the reaction equation must be specified. Consider the combustion of ammonia:
4NH3 + 3O2 = 2N2 + 6H2O
If react 4.00/32 = 0.125 mol we get 0.125*3/2 = 0.1875 mol of N2. Mass of N2 is 0.1875*28 = 5.25 g.
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