We will now derive an expression for the rate of change of temperature with height of a parcel of dry air as it moves about in the Earth’s atmosphere. Since the air parcel undergoes only adiabatic transformations
"dQ=0"
and the atmosphere is in hydrostatic equilibrium.
The gravity side
"dp=-g\\cdot\\rho\\cdot dz"
"\\frac{dp}{\\rho}=-g\\cdot dz"
The thermodynamics side
"-dA=dU \\to-pdV=mc_{V}dT"
"Vdp-d(pV)=mc_{V}dT"
"Vdp-d(nRT)=Vdp-nRdT=mc_{V}dT"
"\\frac{V}{m}dp-\\frac{n}{m}RdT=c_{V}dT"
"\\frac{1}{\\rho}dp-\\frac{n}{nM}RdT=c_{V}dT"
"\\frac{1}{\\rho}dp=(\\frac{R}{M}+c_{V})dT"
"\\frac{dp}{\\rho}=c_{p}dT"
"c_{p}dT=-g\\cdot dz"
And finally
"\\frac{dT}{dz}=-\\frac{g}{c_{p}}".
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