The amount of heat needed to change the temperature of the pot with water is "Q = c_w m_w \\Delta T + c_i m_i \\Delta T", where "\\Delta T" is the change in temperature, "(m_w, c_w), (m_i, c_i)" are specific heat capacities and masses of water and iron respectively.
Specific heat capacities are table values: "c_w = 4200 \\frac{J}{kg \\cdot K}" and "c_i = 450 \\frac{J}{kg \\cdot K}".
Substituting "\\Delta T = 90 K", "m_i = 10 kg, m_w = 10 kg" into above formula for "Q", obtain "Q \\approx 4.2 \\cdot 10^6 J".
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