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a certain gas is compressed reversibly from 1 bar , 17 degrees to a pressure of 5bar in a perfectly thermally insulated cylinder the final temperature being 77degrees . The work done on the gas during the compression is 45kj/Kg. Calculate Cv alpha and R


In a thermodynamic experiment 25kg of water at 95C is mixed with 35kg of water at 35C, the pressure being taken as constant and the temperature of the surrounding being 15C(Cp of water=4.2kJ/kgK). Calculate total available energy, final temperature after mixing and decrease in available energy due to mixing.


on a day when air temperature is 34°c (normal skin temperature) a cyclist is maintaining a speed of 15 km/hr. how many grams of water must this cyclist evaporate each minute to get rid of the body heat produced by his activity?


Every household has at least one refrigerator, many hotels have ice makers and most of us like, you may have wondered how much heat energy a refrigerator/ice maker take from water to make ice. Compute the amount of energy an ice maker extracts from 200g of water at 34°c manufacture ice at 0°c.


(a) Two moles of an ideal gas occupy a volume V. The gas expands isothermally and reversibly to a volume 3V. (i) Is the velocity distribution changed by the isothermal expansion? Explain. (ii) Use Eq. (Microscopic state) to calculate the change in entropy of the gas. (iii) Use Eq. (reversible isothermal process) to calculate the change in entropy of the gas. Compare this result to that obtained in part (ii).


(a) You make tea with 0.250 kg of 85.0 degrees Celsius water and let it cool to room temperature (20.0 degrees Celsius) (i) Calculate the entropy change of the water while it cools. (ii) The cooling process is essentially isothermal for the air in your kitchen. Calculate the change in entropy of the air while the tea cools, assuming that all of the heat lost by the water goes into the air. What is the total entropy change of the system tea + air?


(b) An ice making machine operates in a Carnot cycle. It takes heat from water at 0.0 degrees Celsius and rejects heat to room at 24.0 degrees Celsius. Suppose that 85.0 kg of water at 0.0 _C are converted to 0.0 degrees Celsius. (i) How much heat is discharged into the room? (ii) How much energy must be supplied to the device?


(a) The pV-diagram which shows a cycle of a heat engine that uses 0.250 mol of an ideal gas with g = 1.40. Process ab is adiabatic. (i) Find the pressure of the gas at point a. (ii) How much heat enters this gas per cycle, and where does it happen? (iii) How much heat leaves this gas in a cycle, and where does it occur? (iv) How much work does this engine do in a cycle? (v) What is the thermal efficiency of the engine?


(b) Freezer has a coefficient of performance of 2.40. The freezer is to convert 1.80 kg of water at 25 degrees Celsius to 1.80 kg of ice at -5.0 degrees Celsius in one hour. (i) What amount of heat must be removed from the water at 25 degrees Celsius to convert it to ice at -5.0 degrees Celsius? (ii) How much electrical energy is consumed by the freezer during this hour? (iii) How much wasted heat is delivered to the room in which the freezer sits?


  1. suppose that a heat engine is connected to two energy reservoirs, one a pool of molten aluminum (660 degrees Celsius) and the other a block of solid mercury (-38.9 degrees Celsius). The engine runs by freezing 1.00 g of aluminum and melting 15.0 g of mercury during each cycle. The heat of fusion of aluminum is 3.97 X 105 J/kg; the heat of fusion of mercury is 1.18 X 104 J/kg. What is the efficiency of this engine?
  2. Argon enters a turbine at a rate of 80.0 kg/min, a temperature of 800 degrees Celsius and a pressure of 1.50 MPa. It expands adiabatically as it pushes on the turbine blades and exits at a pressure of 300 kPa.

(a) Calculate its temperature at the time

of exit.

(b) Calculate the (maximum) the

power output of the turning turbine.

(c) The turbine is one component of a

model closed-cycle gas turbine

engine . Calculate the maximum

efficiency of the engine.


 A constant volume gas thermometer containing helium gives readings of gas pressure, ‘p’ of 1000 and 1366 mm of mercury at the ice point and the steam point respectively.

(a) Express the gas thermometer Celsius temperature, ‘tc’ in terms of gas pressure p.

(b) The thermometer, when left standing in the atmosphere, registers 1075 mm. Determine the

atmospheric temperature.



Two moles of an ideal gas occupy a volume V. The gas expands isothermally and reversibly to a volume

3V. (a) Is the velocity distribution changed by the isothermal expansion? Explain. (b) Use Eq.

(Microscopic state) to calculate the change in entropy of the gas. (c) Use Eq. (reversible isothermal

process) to calculate the change in entropy of the gas. Compare this result to that obtained in part (b).