Question #70208

When a monataomic ideal gas expands at a constant pressure of 5.4 x 105 Pa, the volume of the gas increases by 4.6 x 10-3 m3. Determine the heat that flows. If heat flows into the gas, then the heat flow is positive. If the heat flows out of the gas, then the heat flow is negative.
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Expert's answer

2017-09-25T15:25:06-0400

Answer on #70208, Physics / Molecular Physics | Thermodynamics

Question. When a monoatomic ideal gas expands at a constant pressure of 5.4105Pa5.4 \cdot 10^{5} \, \text{Pa}, the volume of the gas increases by 4.6103m34.6 \cdot 10^{-3} \, \text{m}^{3}. Determine the heat that flows. If heat flows into the gas, then the heat flow is positive. If the heat flows out of the gas, then the heat flow is negative.

Given: p=5.4105Pa;p=constp = 5.4 \cdot 10^{5} \, \text{Pa}; p = \text{const}, the process is isobaric.


ΔV=4.6103m3.\Delta V = 4.6 \cdot 10^{-3} \, \text{m}^{3}.


Find: Q?Q - ?.

Solution. In accordance with the first law of thermodynamics


Q=ΔU+A,Q = \Delta U + A,


where QQ – the amount of heat supplied to the system; ΔU\Delta U – the change in the internal energy; AA – the amount of work done by the system.

For the isobaric process


A=pΔV,A = p \cdot \Delta V,


The change in the internal energy


ΔU=mMi2RΔT,\Delta U = \frac{m}{M} \frac{i}{2} R \Delta T,


where ii – degrees of freedom of gas molecules. For a monoatomic ideal gas i=3i = 3.

For the ideal gas


pΔV=mmRΔT.p \cdot \Delta V = \frac{m}{m} R \Delta T.


Finally, we have


Q=ΔU+A=mMi2RΔT+pΔV=mMRΔTi2+pΔV=pΔVi2+pΔV=pΔV(1+i2)==pΔVi+22.\begin{array}{l} Q = \Delta U + A = \frac{m}{M} \frac{i}{2} R \Delta T + p \cdot \Delta V = \frac{m}{M} R \Delta T \frac{i}{2} + p \cdot \Delta V = p \cdot \Delta V \cdot \frac{i}{2} + p \cdot \Delta V = p \cdot \Delta V \cdot \left(1 + \frac{i}{2}\right) = \\ = p \cdot \Delta V \frac{i + 2}{2}. \\ \end{array}Q=pΔVi+22=5.41054.61033+22=+62.1102J.Q = p \cdot \Delta V \cdot \frac{i + 2}{2} = 5.4 \cdot 10^{5} \cdot 4.6 \cdot 10^{-3} \cdot \frac{3 + 2}{2} = +62.1 \cdot 10^{2} \, \text{J}.


Answer: Q=pΔVi+22=+62.1102JQ = p \cdot \Delta V \cdot \frac{i + 2}{2} = +62.1 \cdot 10^{2} \, \text{J}.

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