Answer to Question #247001 in Molecular Physics | Thermodynamics for Nani

Question #247001

While the pressure remains constant at 689.5 kPa the volume of a system of air changes from 0.567 m3 to 0.283 m3. Determine the heat added/rejected


1
Expert's answer
2021-10-06T13:01:03-0400

P=689.5  kPaV1=0.567  m3V2=0.283  m3P=689.5 \; kPa \\ V_1= 0.567 \;m^3 \\ V_2 = 0.283 \;m^3

Assume m=1

Qsup=ΔH=mcpΔT=1.005  kJ/kgK(T2T1)Q_{sup} = ΔH = mc_pΔT \\ = 1.005 \;kJ/kgK(T_2-T_1)

From ideal gas equation

PV1=mRT1T1=689.5×0.5670.287×1=1362.18  KPV2=mRT2T2=689.5×0.2830.287×1T2=679.89  KQsup=ΔH=1.005×(679.891362.18)=685.70  kJPV_1 =mRT_1 \\ T_1 = \frac{689.5 \times 0.567}{0.287 \times 1} = 1362.18 \;K \\ PV_2=mRT_2 \\ T_2 = \frac{689.5 \times 0.283}{0.287 \times 1} \\ T_2 = 679.89 \;K \\ Q_{sup} = ΔH = 1.005 \times (679.89-1362.18) = -685.70 \;kJ


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