When we have the 1-D box, then the energy of the electron in the box can be represents as below
En=E0+2mL2ℏ2π2n2
We know that Fermi level is the energy of the last electron, if we have 2N electron then we can find the mean energy of the electron with the given equation,
Eav=E0+2N2Σ1NEn
⇒Eav=E0+2N2Σ1NEo+2mL2ℏ2π2n2
we know that Σn2=6N(N+1)(2N+1)=3N3+2N2+6N
If we consider N is large value, then we can ignore the second and third terms.
If we assume that there is lots of electron, then Eav=Eo+2mL23Nℏ2π2N3
But, Fermi level Ef=Eo+2mL2ℏ2π2N2
But if Eo=0
Eav=3Ef
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