Question #118847
How much energy does it take to make 500 g of solid lead at 21°C and turn it entirely to liquid lead?
1
Expert's answer
2020-05-29T10:07:34-0400

The total amount of energy required to turn solid lead entirely to liquid lead consists of two parts:


Qtot=Qheat+QmeltQ_{tot} = Q_{heat} + Q_{melt}

where QheatQ_{heat} is the energy required to heat lead up to the melting point and QmeltQ_{melt} is the energy requred to melt the given amount of lead.


The first term:


Qheat=mc(TmeltT0)Q_{heat} = mc(T_{melt}-T_0)

where m=0.5kgm = 0.5 kg is the mass of lead, c=127.5JkgKc = 127.5 \dfrac{J}{kg\cdot K} is the specific heat capacity of lead,Tmelt=600.6KT_{melt} = 600.6 K is the melting point of lead and T0=294.2KT_0 = 294.2 K is the initial temperature (21°C).

Substitute numerical values:


Qheat=mc(TmeltT0)=0.5127.5(600.6294.2)=19.533kJQ_{heat} = mc(T_{melt}-T_0) = 0.5\cdot 127.5\cdot (600.6 - 294.2) = 19.533 kJ


The second term:


Qmelt=mλQ_{melt} = m\lambda

where λ=25kJ/kg\lambda = 25 kJ/kg is the specific heat of fusion of lead.

Substitute numerical values:


Qmelt=mλ=0.525=12.5kJQ_{melt} = m\lambda = 0.5\cdot 25 = 12.5 kJ

The total energy, thus, will be:


Qtot=19.533kJ+12.5kJ=32.033kJ32kJQ_{tot} = 19.533 kJ + 12.5 kJ = 32.033 kJ \approx32 kJ

Answer. It takes 32 kJ to make 500 g of solid lead at 21°C and turn it entirely to liquid lead.


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