Solution
a) for non flow process
This is isothermal process so
Change in internal energy
ΔU=0
P1V1=nT1T1=nP1V1
Where n=0.3452Kg
After putting value of pressures and n then
T1=255.9K
n = m / M
= ( 10 kg )/ ( 28.97 kg/kgmol )
= 0.3452 kgmol
Work done
W=nRTlnP2P1
W=0.3452× 8.314× 255.9ln620KPa96KPa
W=-1370KJ
Now heat
Q=ΔU+ΔWQ=−1370KJ
Now entropy change
ΔS=TQ=255.9−1370KJ
ΔS=−5.354KJ/kelvin
b) now for steady flow
Work done
Ws=0.3452× 8.314× 255.9ln620KPa96KPa
Ws=−1370KJ/min
ΔH=0
ΔKE=210×(602−152)=14 KJ/min
ΔPE=0
Total heat
Q=ΔH+ΔKE+ΔPE+ Ws
Q=-1353KJ/min
Now entropy change
ΔS=TQ=255.9Kelvin−1353KJ/min
ΔS=−5.267 KJ/min-Kelvin
Comments
Where did n=.3452 came from?
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