Solution
a) for non flow process
This is isothermal process so
Change in internal energy
"\\Delta U=0"
"P_1V_1=nT_1\\\\T_1=\\frac{P_1V_1}{n}"
Where n=0.3452Kg
After putting value of pressures and n then
"T_1=255.9K"
n = m / M
= ( 10 kg )/ ( 28.97 kg/kgmol )
= 0.3452 kgmol
Work done
W=nRT"\\ln{\\frac{P_1}{P_2}}"
W=0.3452"\\times" 8.314"\\times" 255.9"\\ln{\\frac{96KPa}{620KPa}}\n\\\\"
W=-1370KJ
Now heat
"Q=\\Delta U+\\Delta W\\\\Q=-1370KJ"
Now entropy change
"\\Delta S=\\frac{Q}{T}=\\frac{-1370KJ}{255.9}"
"\\Delta S=-5.354KJ\/kelvin"
b) now for steady flow
Work done
Ws=0.3452"\\times" 8.314"\\times" 255.9"\\ln{\\frac{96KPa}{620KPa}}\n\\\\"
"W_s=-1370KJ\/min"
"\\Delta H=0"
"\\Delta KE=\\frac{10\\times(60^2-15^2) }{2}=14" KJ/min
"\\Delta PE=0"
Total heat
"Q=\\Delta H+\\Delta KE+\\Delta PE+" Ws
Q=-1353KJ/min
Now entropy change
"\\Delta S=\\frac{Q}{T}=\\frac{-1353KJ\/min}{255.9Kelvin}"
"\\Delta S=-5.267" KJ/min-Kelvin
Comments
Where did n=.3452 came from?
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