A charged particle moving in a magnetic field may experience Lorentz's force, which depends on particle's velocity, charge, the field magnitude, and the orientation of the field with regard to the velocity:
That is why any charged particle where the angle between and is not , experiences some force. Also, we can place an electric field to "compensate" the influence of the magnetic field and it will seem that the particle will move in a straight line, but actually it will experience two opposite but equal forces.
So without an electric field if is parallel to , i.e. the particle moves along the field lines, the force is zero.
Comments