Semiconductors are usually made of chemical elements that belong to the IV group. It means that these elements have 4 valence (free and ready to make bonds) electrons. To make it a real semiconductor we can add an acceptor of donor element. Donor elements have 5 valence electrons, which form 4 bonds with 4 valence electrons of main element and one electron of donor is weakly bonded. One “liberated” electron thus becomes a charge carrier and can carry a current. This is how n-type semiconductors are made.
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