Oxygen (molar mass 32 kg/kmol) expands reversibly in a cylinder behind a piston at a constant pressure of 3 bar. The volume initially is 0.0114 m3 and finally is 0,0319m3 , the initial temperature is 16.380C. Calculate the absolute temperature after expansion with the correct unit. Assume oxygen to be a perfect gas and take the specific heat at constant pressure as = 0.917kj/kgK.
molar mass = 32 kg/kmol
P = constant
P = 3 bar
V1 = 0.01m3 V2 = 0.03m3
TI= 170C = 290.15K
W = ?
Q = ?
Constant Pressure (Cp) = 0.917kj/kgK
Therefore,
W = P(V2 – V1) = 3 × 102 (0.0319 – 0.0114)
W = 6.15 KJ/6150J
3⋅105 (0.01) = m/32 (8.31) (290)
m = 39.8165g/ 0.039Kg
n = 39.8165g/32
n = 1.2443 mol
Q = m Cp ∆T
Q = 0.039 × 0.917 × (870 – 290.15)
Q = 20. 74KJ/ 20740J
3.105 (0.03) = m/32 (8.31) T2
T2 = 870k
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