A piston–cylinder device contains 1.2 kg of nitrogen gas at 120 kPa and 27°C. The gas is now compressed slowly in a polytropic process during which PV1.3 = constant. The process ends when the volume is reduced by one-half. Determine the entropy change of nitrogen during this process.
Solution;
From the tables;
"R=0.297kJ\/kgK"
"C_v=0.743kJ\/kgK"
From the polytropic relation;
"\\frac{T_2}{T_1}=(\\frac{v_1}{v_2})^{n-1}"
"T_2=300(2)^{0.3}=369.34K"
Change in entropy;
"\\Delta s=m[C_vln(\\frac{T_2}{T_1})+Rln(\\frac{v_2}{v_1})]"
"\\Delta s=1.2[0.743ln(\\frac{369.34}{300})+0.297ln(0.5)]"
"\\Delta s=-0.0616kJ\/K"
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