Question #79126

0.5kg of air is compressed reversibly and adiabatically from 80kpa, 60°c to 0.4Mpa and is then expanded at constant pressure to the original volume. Calculate the heat transfer and work transfer for the whole path.
Take R = 0.247kj/kg.k, Cp = 1.005kj/kg.k, Cv = 0.718kj/kg.k

Expert's answer

Question #79126

0.5kg of air is compressed reversibly and adiabatically from 80kPa, 60C60^{\circ}\mathrm{C} to 0.4Mpa and is then expanded at constant pressure to the original volume. Calculate the heat transfer and work transfer for the whole path.

Take R=0.247kJ/kg.KR = 0.247\mathrm{kJ / kg.K}, Cp=1.005kJ/kg.KC_p = 1.005\mathrm{kJ / kg.K}, Cv=0.718kJ/kg.KC_v = 0.718\mathrm{kJ / kg.K}

Answer:

Assume the air is an ideal gas. Thus, from the ideal gas equation we have:


pV=mRT,pV = mRT,


where pp, VV and TT are pressure, volume and absolute temperature, respectively,

m=0.5kgm = 0.5\mathrm{kg} – the mass of the air (which remains constant),

R=0.247kJ/kg.KR = 0.247\mathrm{kJ / kg.K} – the gas constant of air.

From (1) we can find the initial volume of the processed air (T0=60C+273K=333KT_0 = 60^{\circ}\mathrm{C} + 273\mathrm{K} = 333\mathrm{K}):


V0=mRT0p0=0.50.24733380=0.514m3.V_0 = \frac{mRT_0}{p_0} = \frac{0.5 \cdot 0.247 \cdot 333}{80} = 0.514\mathrm{m^3}.


Since the compression is reversible and adiabatic, the heat transfer is zero (Qc=0Q_c = 0), and the transferred work is given by:


Wc=αmRT0((p1p0)γ1γ1),W_c = -\alpha mRT_0 \left(\left(\frac{p_1}{p_0}\right)^{\frac{\gamma - 1}{\gamma}} - 1\right),


where


γ=CpCV,\gamma = \frac{C_p}{C_V},


the adiabatic index,

α=2.5\alpha = 2.5 – the number of degrees of freedom (which is 5 for the air) divided by two.

Substitute into (3) and (2):


γ=1.0050.718=1.400,\gamma = \frac{1.005}{0.718} = 1.400,Wc=2.50.50.247333((40080)1.411.41)=60.00kJ.W_c = -2.5 \cdot 0.5 \cdot 0.247 \cdot 333 \left(\left(\frac{400}{80}\right)^{\frac{1.4 - 1}{1.4}} - 1\right) = -60.00\mathrm{kJ}.


The final volume of the air could be determined from the equation of an adiabatic process:


p0V0γ=p1V1γ,p_0 V_0^{\gamma} = p_1 V_1^{\gamma},V1=V0(p0p1)1γ=0.514(80400)11.4=0.163m3.V_1 = V_0 \left(\frac{p_0}{p_1}\right)^{\frac{1}{\gamma}} = 0.514 \cdot \left(\frac{80}{400}\right)^{\frac{1}{1.4}} = 0.163\mathrm{m^3}.


The temperature at the end of compression could be defined from (1) as follow:


T1=p1V1mR=4000.1630.50.247=527.3K.T _ {1} = \frac {p _ {1} V _ {1}}{m R} = \frac {4 0 0 \cdot 0 . 1 6 3}{0 . 5 \cdot 0 . 2 4 7} = 5 2 7. 3 \mathrm {K}.


For the second process, which is isobaric expansion, the heat and the work transfer, respectively, are given by:


Q=mCpΔT,Q = m C _ {p} \Delta T,W=pΔV,W = p \Delta V,


where ΔT\Delta T and ΔV\Delta V are change in temperature and volume, respectively.

From (1), the final temperature of the air is:


T2=p2V2mR=4000.5140.50.247=1664.8K.T _ {2} = \frac {p _ {2} V _ {2}}{m R} = \frac {4 0 0 \cdot 0 . 5 1 4}{0 . 5 \cdot 0 . 2 4 7} = 1 6 6 4. 8 \mathrm {K}.


Substitute into (5) and (6):


Qe=0.51.005(1664.8527.3)=571.7kJ,Q _ {e} = 0. 5 \cdot 1. 0 0 5 \cdot (1 6 6 4. 8 - 5 2 7. 3) = 5 7 1. 7 \mathrm {k J},We=400(0.5140.163)=140.5kJ.W _ {e} = 4 0 0 \cdot (0. 5 1 4 - 0. 1 6 3) = 1 4 0. 5 \mathrm {k J}.


The total heat transfer is:


Q=Qc+Qe=571.7kJ.Q = Q _ {c} + Q _ {e} = 5 7 1. 7 \mathrm {k J}.


The total work transfer is:


W=60+140.5=80.5kJ.W = - 6 0 + 1 4 0. 5 = 8 0. 5 \mathrm {k J}.

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