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1. Under what situation shall engineers use jacking at one end only and from both ends in prestressing work?


If 8.5 moles of propylene(gas) reacts completely with hydrogen to form propane(liq). Determine the total heat of reaction(KJ) at 25 oC and 1 atm.


Methane reacts completely with oxygen to produce carbon dioxide(gas) and water(liq). What is the extent of reaction if 105 moles of water(liq) are produced?

Just write the final answer correct to 2 decimal places. Show all workings.

How will you prepare 10 ml of 0.025 M acetate buffer (pH 4.33) from stock solution of 0.05 M acetic acid
and 0.03 M sodium hydroxide ?

a) We are planning to operate a mixed flow reactor to convert A into R. This is a liquid phase reaction, with the stoichiometryA→R. The rate of reaction is given below. What size of mixed flow reactor is needed to achieve 75% conversion of a feed stream of 1000 moles of A per hour?

CA,mol/l. 0.1 0.2 0.3 04 0.5 0.6 0.7 0.8 1 1.3 2. -rA,mol/(l.min). 0.1 0.3 0.5 0.6 0.5 0.25 0.1 0.06 0.05 0.045 0.042

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At present the conversion is 66.7% for the elementary second order reaction 2A→2R when operating in an isothermal plug flow reactor with a recycle ratio of unity. Determine the conversion if recycle is shut off.

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Gaseous reactant A decomposes as per the following reaction stoichiometry and kineticsA→3R.-rA= 0.60CA mol/l min. Determine the conversion of A in a 50 % A +50% inerts fed at 180 l/min.(330mmol/min) to a 1000 liter mixed flow reactor.
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A high molecular weight hydrocarbon stream A is continuously fed to a mixed flow reactor where it thermally cracks into lower molecular materials, collectively called R, as per stoichiometryd A→5R. It is a homogencus gas phase reaction Different extents of cracking obtained by varying the feed rate to the reactor are as follows:

FAo(milli mol/h) 300 1000 3000 5000

CA,OUT (milli mol/l). 16 30 5 60. The reactor volume is 0.1 liter and the feed concentration at the temperature of the reactor is Cac =100 milli mol/l. Find the rate equation which satisfactorily represents the cracking reaction. in the above problem if we ignore density changes, what is the rate equation represents the reaction.
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b) Nitrous oxide decomposes according to the second order rate equation 2N₂0→2N₂ +0₂ The rate constant is 977 cm

An evaporator is used to concentrate 12 000 kg/h of a 15% solution of NaOH entering at 60oC to a product of 50% solid. The pressure of the saturated steam used is 300 kPa and the pressure in the vapour space of the evaporator is 11.7 kPa. The overall heat transfer coefficient is 1 560 W/m2K. Calculate the steam used and the steam economy in kg vaporised/kg steam.


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