Answer to Question #300204 in Chemical Engineering for Manika

Question

A mixture of benzene and toluene containing 40 mole % of benzene is to be separated to give a product of 90 mole % benzene at top and a bottom product with not more than 10mole % benzene. Using an average value of 2.4 for relative volatility of benzene relative to toluene, calculate the number of theoretical plates required at total reflux. Also calculate the minimum reflux ratio, if the feed is liquid and is at its boiling point

Answer 1

The equilibrium curve relationship is given by y = ax/(1 + x(a - 1)) = 2.4x/(1 + 1.4x)

At total reflux, operating line coincides with y = x line. The above equation can be written as,

1 + 1.4x = 2.4x/y

1/x + 1.4 = 2.4/y

1/x = 2.4/y - 1.4 = (2.4 - 1.4y)/y i.e.,

x = y/(2.4 - 1.4y)

We can find analytically, the minimum number of theoretical plates using the above equations as given below:

Starting from the conditions at the top of the distillation column, y_D = 0.9

For the tray 1:

y₁ = 0.9 and x₁ = 0.9/(2.4 - 1.4 x 0.9) = 0.7895

For the tray 2:

y₂ = 0.7895 and x₂ = 0.7895/(2.4 - 1.4 x 0.7895) = 0.6098

For the tray 3:

y₃ = 0.6098 and x₃ = 0.6098/(2.4 - 1.4 x 0.6098) = 0.3944

For the tray 4:

y₄ = 0.3944 and x₄ = 0.3944/(2.4 - 1.4 x 0.3944) = 0.2134

For the tray 5:

y₅ = 0.2134 and x₅ = 0.2134/(2.4 - 1.4 x 0.2134) = 0.1016

For the tray 6:

y₆ = 0.1016 and x₆ = 0.1016/(2.4 - 1.4 x 0.1016) = 0.045

Since x_W is only 0.1, we are having fractional tray here. It is estimated as below:

Fractional tray = (0.1016 - 0.1) / (0.1016 - 0.045) = 0.03

Number of theoretical plates including reboiler = 5 + 0.03 = 5.03

The number of theoretical plates at total reflux can also be estimated from Fenske's equation, which is given as,

N_m + 1 = ( log (x_D (1 - x_W) ) / ( (1 - x_D) x_W) ) / log a_avg

Where N_m + 1 is the minimum number of theoretical stages including the reboiler.

In our problem, x_D = 0.9; x_W = 0.1; a_avg = 2.4

N_m + 1 = 5.02

Calculation of Minimum Reflux ratio:

For the saturated liquid feed, at minimum reflux, 'q' line and enriching operating line cuts at x = z_F = 0.4 and y = 2.4z_F/(1 + 1.4z_F) = 2.4 x 0.4/(1 + 1.4 x 0.4) = 0.6154

Therefore, the enriching operating line passes through the points (0.9,0.9) and (0.4, 0.6154).

The intersection point of the enriching operating line at the y axis (which is equal to x_D/(R_m + 1), say y_I ) is calculated as follows:

 Slope = (0.9 - 0.6154)/(0.9 - 0.4) = 0.2846/0.5 = 0.5692

This is the slope of the line connecting (0.4, 0.6154) and (0, y_I)

 (0.6154 - y_I) / (0.4 - 0) = 0.5692

y_I = 0.3877 i.e.,

x_D/(R_m + 1) = 0.3877

0.9/(R_m + 1) = 0.3877

R_m = 1.321