If 15.0 mol of C3H8 react with 4.5 mol of O2 which is the limiting reagent? Which is the excess reagent?
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If the actual yield of CO2 is 150g, what is the percent yield of CO2?
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11. Describe the formation of outer orbit complex [Ni(H2O)6]2+ ion using VBT
11. Describe bonding in [Mn(CN)6]3- using VBT
State the hybridisation state of the metal, predict the geometry and magnetic property of the complex
11. Which of the following elements form diatomic molecule held together by triple covalent bonds?
(a) Oxygen (b) Lithium (c ) carbon (d) Nitrogen
11. Molecular orbital model is based upon which of the following models ?
(a) Classical model (b) Bohr model) (c ) Quantum mechanical model (d) Democritus model
The antibiotic thiarubin-A was discovered by studying the feeding habits of wild
chimpanzees in Tanzania. The structure for thiarubin-A is
a. Complete the Lewis structure showing all lone pairs of electrons.
b. Indicate the hybrid orbitals used by the carbon and sulfur atoms in thiarubin-A.
c. How many σ and π bonds are present in this molecule?
One of the first drugs to be approved for use in treatment of acquired immune deficiency
syndrome (AIDS) was azidothymidine (AZT). Complete the Lewis structure for AZT.
a. How many carbon atoms are sp3 hybridized?
b. How many carbon atoms are sp2 hybridized?
c. Which atom is sp hybridized?
d. How many σ bonds are in the molecule?
e. How many π bonds are in the molecule?
f. What is the N=N=N bond angle in the azide (–N3) group?
g. What is the H–O–C bond angle in the side group attached to the five-membered ring?
h. What is the hybridization of the oxygen atom in the –CH2OH group?
. Urea, a compound formed in the liver, is one of the ways humans excrete nitrogen.
The Lewis structure for urea is
Using hybrid orbitals for carbon, nitrogen, and oxygen, determine which orbitals overlap
to form the various bonds in urea.
1. The following ions are best described with resonance structures. Draw the resonance structures, and using formal charge arguments, predict the best Lewis structure for each ion. a. NCO- b. CNO-